全文获取类型
收费全文 | 153625篇 |
免费 | 12656篇 |
国内免费 | 6854篇 |
学科分类
工业技术 | 173135篇 |
出版年
2024年 | 245篇 |
2023年 | 1719篇 |
2022年 | 2782篇 |
2021年 | 5099篇 |
2020年 | 3755篇 |
2019年 | 3331篇 |
2018年 | 3838篇 |
2017年 | 4239篇 |
2016年 | 4411篇 |
2015年 | 5436篇 |
2014年 | 7326篇 |
2013年 | 9615篇 |
2012年 | 10566篇 |
2011年 | 12046篇 |
2010年 | 10626篇 |
2009年 | 10500篇 |
2008年 | 10344篇 |
2007年 | 9654篇 |
2006年 | 8952篇 |
2005年 | 7279篇 |
2004年 | 5789篇 |
2003年 | 4915篇 |
2002年 | 4771篇 |
2001年 | 3941篇 |
2000年 | 3288篇 |
1999年 | 2670篇 |
1998年 | 3077篇 |
1997年 | 2167篇 |
1996年 | 1724篇 |
1995年 | 1456篇 |
1994年 | 1099篇 |
1993年 | 971篇 |
1992年 | 679篇 |
1991年 | 649篇 |
1990年 | 532篇 |
1989年 | 510篇 |
1988年 | 379篇 |
1987年 | 327篇 |
1986年 | 303篇 |
1985年 | 248篇 |
1984年 | 217篇 |
1983年 | 176篇 |
1982年 | 167篇 |
1981年 | 148篇 |
1980年 | 141篇 |
1979年 | 110篇 |
1978年 | 97篇 |
1977年 | 130篇 |
1976年 | 161篇 |
1975年 | 79篇 |
排序方式: 共有10000条查询结果,搜索用时 93 毫秒
991.
992.
A novel fully conjugated polymer containing 1,10‐phenanthroline (DAPcDOD) was first synthesized by the polycondensation of 2,7‐dimethyl‐2,4,6‐octatriene‐1,8‐dial with 5,6‐diamine‐1,10‐phenanthroline. Three polymeric complexes were first prepared by the reaction of DAPcDOD with NiSO4, CoCl2, and FeSO4, respectively. The structures of the polymer and the complexes were characterized by IR, 1H‐NMR, and elemental analysis. The magnetic behaviors of these complexes were measured as a function of magnetic field strength (0–50 kOe) at 5 K and as a function of temperature (5–300 K) at a magnetic field strength of 30 kOe. The results show that DAPcDOD–Ni2+ and DAPcDOD–Co2+ were soft ferromagnets, whereas DAPcDOD–Fe2+ exhibited the features of an antiferromagnet. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
993.
Hsu‐Wei Fang Hsien‐Chieh Wang Teh‐Hua Tsai Wei‐Bor Tsai Shao‐Yi Hou Hsuan‐Liang Liu Wun‐Hsing Lee Yung‐Chang Lu Chun‐Hsiung Huang 《应用聚合物科学杂志》2008,108(4):2428-2437
Wear of ultrahigh‐molecular‐weight polyethylene (UHMWPE) and wear‐particle‐induced osteolysis and bone resorption are the major factors causing the failure of total joint replacements. It is feasible to improve the lubrication and reduce the wear of artificial joints. We need further understanding of the lubrication mechanism of the synovial fluid. The objective of this study is to evaluate the lubricating ability of three major components in the synovial fluid: albumin, globulin, and phospholipids. An accelerated wear testing procedure in which UHMWPE is rubbed against a microfabricated surface with controlled asperities has been developed to evaluate the lubrication behavior. An analysis of the wear particle dimensions and wear amount of the tests has provided insights for comparing their lubrication performance. It is concluded that the presence of biomolecules at the articulating interface may reduce friction. A higher concentration of a biological lubricant leads to a decrease in the wear particle width. In addition, in combination with the wear results and mechanical analysis, the roles of individual biomolecules contributing to friction and wear at the articulating interface are discussed. These results can help us to identify the role of the biomolecules in the boundary lubrication of artificial joints, and further development of lubricating additives for artificial joints may be feasible. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
994.
The drawability of iodinated at solution before casting (IBC) polyvinyl alcohol films prepared by casting aqueous solutions of 10 wt % PVA containing 15.2, 39.8, 83.2, 117.0, and 140.1% was examined with a tensile tester at 20–60°C. The tensile behavior of IBC films showed that the yield and breaking loads were much lower, and the breaking elongation was even higher than those of the unoriented iodinated after casting (IAC) films as well as the untreated PVA films. The maximum draw ratios of the films with the weight gain of 15.2, 39.8, 83.2, 117, and 140.1% were 4.5, 5.5, 8.5, 8.0, and 7.5, respectively, which were achieved at 20°C in all. The crystallinity of all films increased by the maximum draw, regardless of crystallinity before drawing. The crystalline structure was recovered to the original PVA crystalline lattice by deiodination. Amorphous orientation and initial moduli increased with the maximum draw ratio, while the orientation of crystals was constant. The orientation and moduli increased up to the weight gain of 83.2%, whose highest draw ratio and initial modulus were 8.5 and of 7.1 GPa, respectively, and then decreased. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
995.
Quantitative analysis of isothermal crystallization kinetics of PLA/clay nanocomposite and PLA/clay/regenerated cellulose fiber (RCF) hybrid composite has been conducted. The crystallization rate constant (k) according to Avrami equation was higher in PLA/clay nanocomposite than in PLA/clay/RCF hybrid composite at the same crystallization temperature. The equilibrium melting temperature obtained by Hoffman–Weeks equation was almost same in both composites, whereas stability parameter was greater in hybrid composite than in nanocomposite. Activation energy of hybrid composite for crystallization was larger than that of nanocomposite. The value of nucleation parameter (Kg) and surface free energy (se) of hybrid composite were larger than nanocomposite, indicating that hybrid composite has a less folding regularity than nanocomposite. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
996.
Free radicals are formed upon irradiation of polymers. The annealing of γ-ray irradiated syndiotactic polystyrene (sPS) with doses 10, 23 and 36 kGy was studied with electron paramagnetic resonance (EPR) spectroscopy. The EPR spectra are possibly attributed to three types of radicals, (a) the benzyl radical Ra, (b) resonance structure of the phenyl radical Rb, and (c) carbon-superoxide-centered radical Rc with three-, four-, and single-line features, respectively. Radical Ra can be easily formed by the removal of the proton from the tertiary carbon; radical Rb is created from delocalization of the spin of the radical Ra onto the benzene ring; and radical Rc may be generated from the interaction of a carbon-centered radical with dioxygen from the air which forms a carbon-superoxide center. By comparing EPR spectra of the radicals with a DPPH standard, the spin numbers of the radicals can be calculated. The spin number of all radicals decreases exponentially with time in the temperature range of 60-90 °C regardless of dose of the irradiation. The annealing of Ra, Rb, and Rc follows first-order kinetics. The activation energies of the annihilation are determined to be 15.8-19.0, 16.0-19.5, and 23.2-26.6 kJ/mol for radicals Ra, Rb, and Rc, respectively. The kinetic study presented herein can serve as a criterion for γ-ray irradiation process in various applications, such as sterilization of polymer materials and devices. 相似文献
997.
998.
Non-contact measurement of the mechanical properties of materials using an all-optical technique 总被引:1,自引:0,他引:1
Describes an optically-based measurement mechanism which realizes a totally noncontact assessment of the most important mechanical properties of structural materials - namely effective stiffness and Poisson ratio. These parameters are sensitive indicators of material integrity. The technique uses laser generated broadband ultrasound as a probe and interferometric optical detection as the detector again exploiting the broadband capability of optics in both space and time. Both detection and excitation systems are most conveniently realized in practical systems through optical fiber linkages. Observing the coupled waveforms between source and detector as a function of source: detector separation after a space : time Fourier transform yields a set of dispersion curves for the ultrasonic (typically Lamb wave) transfer function of the sample. This, in turn, can be inverted using curve fitting routines to obtain effective values of modulus and stiffness. An initial assessment of this inversion process is presented and demonstrates that the effective modulus can be extracted with a confidence level of better than a few percent with slightly larger errors in the Poisson ratio. 相似文献
999.
Diode lasers used to pump high average power solid-state lasers typically have broad spectral width so that most of the pump light is not at the peak of the gain medium's absorption feature. However, the long absorption length in these lasers enables even weakly absorbed light to pump efficiently. The result is that high absorption efficiency and improved pump distribution uniformity are possible when using realistic pump diodes. In addition, both quantities are nearly independent of the pump center wavelength. 相似文献
1000.